Gmb. Parkes et al., New concepts in sample controlled thermal analysis: Resolution in the timeand temperature domains, ANALYT CHEM, 71(13), 1999, pp. 2482-2487
This paper describes the concepts of resolution in the time and temperature
domains and illustrates the principles using two new sample controlled the
rmal analysis (SCTA) techniques. The use of SCTA, where the sample temperat
ure is determined by the rate of reaction, offers a number of advantages ov
er conventional (linear heating) thermal analysis methods. The operation, a
dvantages, and disadvantages of the two new techniques are discussed with e
xamples.