An anhydrous sol-gel system derived from methyldichlorosilane

Authors
Kim, DS Kroke, E Riedel, R Gabriel, AO Shim, SC
Citation
Ds. Kim et al., An anhydrous sol-gel system derived from methyldichlorosilane, APPL ORGAN, 13(7), 1999, pp. 495-499
Citations number
16
Categorie Soggetti
Chemistry
Journal title
APPLIED ORGANOMETALLIC CHEMISTRY
ISSN journal
02682605 → ACNP
Volume
13
Issue
7
Year of publication
1999
Pages
495 - 499
Database
ISI
SICI code
0268-2605(199907)13:7<495:AASSDF>2.0.ZU;2-1
Abstract
Pyridine-catalyzed reactions of methyldichlorosilane with bis(trimethylsily l) carbodiimide afford a dichlorosilane-derived anhydrous sol-gel material. Both trimethylchlorosilane formation and Si-H disproportionation act as cr osslinking mechanisms. The dried gels form amorphous or crystalline materia ls, depending on the sample history. The xerogels gave Si/C/N ceramics when pyrolyzed at 1200 degrees C, Copyright (C) 1999 John Wiley & Sons, Ltd.