We have grown unstrained Al0.66In0.34As0.85Sb0.15/Ga0.64In0.36As0.84Sb0.16
multiple-quantum-well (MQW) structures on InP substrates by metalorganic va
por phase epitaxy. Low-temperature photoluminescence was performed for thes
e MQW structures. By comparing the luminescence peak energies with the theo
retical calculations, we estimated the conduction-band offset ratio to be 0
.75 +/- 0.10 for the Al0.66In0.34As0.85Sb0.15/Ga0.64In0.36As0.84Sb0.16 hete
rostructure. (C) 1999 American Institute of Physics. [S0003-6951(99)02528-0
].