Ligand reorganization energies as a basis for the design of synergistic metal ion extraction systems

Authors
Dietz, ML Bond, AH Hay, BP Chiarizia, R Huber, VJ Herlinger, AW
Citation
Ml. Dietz et al., Ligand reorganization energies as a basis for the design of synergistic metal ion extraction systems, CHEM COMMUN, (13), 1999, pp. 1177-1178
Citations number
11
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
13
Year of publication
1999
Pages
1177 - 1178
Database
ISI
SICI code
1359-7345(19990707):13<1177:LREAAB>2.0.ZU;2-D
Abstract
In the extraction of alkaline earth cations by acidic organophosphorus extr actants, a correlation has been demonstrated between the effectiveness of t he stereoisomers of dicyclohexano-18-crown-6 as synergists and the strain e nergy associated with conversion of the unbound crown ether to its complexe d form.