'Adding' stable functional complementary, nucleophilic and electrophilic clusters: a synthetic route to [{(SiW11O39)Mo3S4(H2O)(3)(mu-OH)}(2)](10-) and [{(P2W17O61)Mo3S4(H2O)(3)(mu-OH)}(2)](14-) as examples

Authors
Muller, A Fedin, VP Kuhlmann, C Fenske, HD Baum, G Bogge, H Hauptfleisch, B
Citation
A. Muller et al., 'Adding' stable functional complementary, nucleophilic and electrophilic clusters: a synthetic route to [{(SiW11O39)Mo3S4(H2O)(3)(mu-OH)}(2)](10-) and [{(P2W17O61)Mo3S4(H2O)(3)(mu-OH)}(2)](14-) as examples, CHEM COMMUN, (13), 1999, pp. 1189-1190
Citations number
22
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
13
Year of publication
1999
Pages
1189 - 1190
Database
ISI
SICI code
1359-7345(19990707):13<1189:'SFCNA>2.0.ZU;2-9
Abstract
Stable functional complementary clusters, i.e. of the electrophilic and nuc leophilic type, can be 'added' resulting in the planned formation of the re lated reaction products: the high-yield synthesis of the crystalline compou nds [Me2NH2](10)- [{(SiW11O39)Mo3S4(H2O)(3)(mu-OH)}(2)]. 20H(2)O 1 and [Me2 NH2](14)[{(P2W17O61)Mo3S4(H2O)(3)(mu-OH)}(2)]. 25H(2)O 2 containing the rel ated {Mo3S4}(4+) as well as {W11O39}(8-) and {W17O61}(10-) clusters as cons tituents, respectively, is a good example.