Synthesis of carbocycles by insertion of 1,1-dihalo-1-lithio species into zirconacycles

Authors
Vicart, N Whitby, RJ
Citation
N. Vicart et Rj. Whitby, Synthesis of carbocycles by insertion of 1,1-dihalo-1-lithio species into zirconacycles, CHEM COMMUN, (13), 1999, pp. 1241-1242
Citations number
22
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
13
Year of publication
1999
Pages
1241 - 1242
Database
ISI
SICI code
1359-7345(19990707):13<1241:SOCBIO>2.0.ZU;2-I
Abstract
1,1-Dihalo-1-lithio species (halogenocarbenoids) undergo double insertion i nto the carbon-zirconium bonds of a zirconacyclopent-ane or -ene to produce , after hydrolysis, bicyclo[3.3.0]oct-anes and -enes.