Cooperative halide, perrhenate anion-sodium cation binding and pertechnetate extraction and transport by a novel tripodal tris(amido benzo-15-crown-5) ligand

Authors
Beer, PD Hopkins, PK McKinney, JD
Citation
Pd. Beer et al., Cooperative halide, perrhenate anion-sodium cation binding and pertechnetate extraction and transport by a novel tripodal tris(amido benzo-15-crown-5) ligand, CHEM COMMUN, (13), 1999, pp. 1253-1254
Citations number
15
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
13
Year of publication
1999
Pages
1253 - 1254
Database
ISI
SICI code
1359-7345(19990707):13<1253:CHPACB>2.0.ZU;2-B
Abstract
A new tripodal tris(amido benzo-15-crown-5) ligand L-1 cooperatively binds chloride, iodide and perrhenate anions via co-bound crown ether complexed s odium cations and efficiently extracts and transports the pertechnetate ani on from simulated aqueous nuclear waste solutions via cooperative ion-pair binding effects.