An extremely mild and stereocontrolled construction of 1,2-cis-alpha-glycosidic linkages via benzyl-protected glycopyranosyl diethyl phosphites

Authors
Tanaka, H Sakamoto, H Sano, A Nakamura, S Nakajima, M Hashimoto, S
Citation
H. Tanaka et al., An extremely mild and stereocontrolled construction of 1,2-cis-alpha-glycosidic linkages via benzyl-protected glycopyranosyl diethyl phosphites, CHEM COMMUN, (13), 1999, pp. 1259-1260
Citations number
26
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
13
Year of publication
1999
Pages
1259 - 1260
Database
ISI
SICI code
1359-7345(19990707):13<1259:AEMASC>2.0.ZU;2-0
Abstract
A highly stereocontrolled 1,2-cis-alpha-glycosidation reaction under condit ions mild enough for acid-labile alcohols has been developed using benzyl-p rotected glycopyranosyl diethyl phosphites as glycosyl donors in the presen ce of 2,6-di-tert-butylpyridinium iodide and tetrabutylammonium iodide.