Optical resolution of chirally functionalized [60]fullerene through formation of diastereomeric methoxyphenylacetic acid esters

Citation
H. Isobe et al., Optical resolution of chirally functionalized [60]fullerene through formation of diastereomeric methoxyphenylacetic acid esters, FUL SCI TEC, 7(4), 1999, pp. 519-528
Citations number
26
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
FULLERENE SCIENCE AND TECHNOLOGY
ISSN journal
1064122X → ACNP
Volume
7
Issue
4
Year of publication
1999
Pages
519 - 528
Database
ISI
SICI code
1064-122X(1999)7:4<519:OROCF[>2.0.ZU;2-B
Abstract
Optical resolution of chirally functionalized [60]fullerene has been achiev ed through formation of diastereomeric alpha-methoxyphenylacetic acid (MPA) esters. The diastereomeric ester products were easily separated either by open column silica gel chromatography or by high pressure liquid chromatogr aphy (HPLC) with BuckyPrep(R) column.