Sugar vanadates: Synthesis and characterization of a mannopyranoside esterincorporating VO3+

Authors
Rajak, KK Rath, SP Mondal, S Chakravorty, A
Citation
Kk. Rajak et al., Sugar vanadates: Synthesis and characterization of a mannopyranoside esterincorporating VO3+, I J CHEM A, 38(5), 1999, pp. 405-406
Citations number
17
Categorie Soggetti
Chemistry
Journal title
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY
ISSN journal
03764710 → ACNP
Volume
38
Issue
5
Year of publication
1999
Pages
405 - 406
Database
ISI
SICI code
0376-4710(199905)38:5<405:SVSACO>2.0.ZU;2-6
Abstract
The reaction of methyl-4,6-dimethoxy-alpha-D-mannopyranoside (H(2)man) with [(VO)-O-IV(L)(H2O)] (L2-, deprotonated salicylaldimine of glycine) in air has afforded [(VO)-O-V(Hman)(L)] in which the sugar ligand is chelated to t he metal via alkoxidic and alcoholic oxygen atoms, the V-O lengths being 1. 799(7) Angstrom and 2.366(8) Angstrom respectively.