Synthesis, structure and separation of a new chiral metal cluster (mu(3)-S)FeCoMo(CO)(8){C5H4C(O)C6H4C(O)OCH3-4} on an amylopectin tris-(phenylcarbamate) chiral column by HPLC

Authors
Zhou, ZG Ding, ER Hou, JG Chen, LR
Citation
Zg. Zhou et al., Synthesis, structure and separation of a new chiral metal cluster (mu(3)-S)FeCoMo(CO)(8){C5H4C(O)C6H4C(O)OCH3-4} on an amylopectin tris-(phenylcarbamate) chiral column by HPLC, I J CHEM A, 38(5), 1999, pp. 411-415
Citations number
16
Categorie Soggetti
Chemistry
Journal title
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY
ISSN journal
03764710 → ACNP
Volume
38
Issue
5
Year of publication
1999
Pages
411 - 415
Database
ISI
SICI code
0376-4710(199905)38:5<411:SSASOA>2.0.ZU;2-A
Abstract
Preparation of amylopectin tris(phenylcarbamate) (ATP) chiral stationary ph ases (CSPs) coated on small-particle (5 mu m, 120 Angstrom) spherical silic a support is reported. A new chiral tetrahedral cluster FeCoMo(mu(3)-S) (CO )(8){C5H4C(O)C6H4C(O)OCH3-4} (2) has been synthesized by the thermal reacti on of the precursor (mu(3)-S)FeCo2(CO)(9) with functionally substituted cyc lopentadienyl tricarbonyl metal anion [Mo(CO)(3)C5H4C(O)CH3] and it has bee n resolved on the amylopectin tris (phenylcarbamate) chiral stationary phas e.