Citation
Ccs. Cavalheiro et al., Photophysics and photoredox properties of the tungsten carbyne complex Cp{P(OPh)(3)}(CO)W CPh, INORG CHEM, 38(13), 1999, pp. 3254
Citations number
40
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669
→ ACNP
Volume
38
Issue
13
Year of publication
1999
Database
ISI
SICI code
0020-1669(19990628)38:13<3254:PAPPOT>2.0.ZU;2-1
Abstract
Studies of photoinduced electron transfer from Cp{P(OPh)(3)}(CO)W=CPh (1) t
o a series of pyridinium and nitroaromatic electron accepters demonstrate t
hat the excited state is a powerful reducing agent with E-1/2(1*/1(+.)) = -
1.7 +/- 0.2 V.