Carboxamido nitrogens are good donors for Fe(III): Syntheses, structures, and properties of two low-spin nonmacrocyclic iron(III) complexes with tetracarboxamido-N coordination

Authors
Marlin, DS Olmstead, MM Mascharak, PK
Citation
Ds. Marlin et al., Carboxamido nitrogens are good donors for Fe(III): Syntheses, structures, and properties of two low-spin nonmacrocyclic iron(III) complexes with tetracarboxamido-N coordination, INORG CHEM, 38(13), 1999, pp. 3258
Citations number
21
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
38
Issue
13
Year of publication
1999
Database
ISI
SICI code
0020-1669(19990628)38:13<3258:CNAGDF>2.0.ZU;2-T
Abstract
Two nonmacrocyclic ligands with pyridine and carboxamide nitrogens as donor s readily form his complexes of the type [(FeL2)-L-III](+) in which the Fe( III) centers exhibit preference for coordination to carboxamido nitrogens o ver pyridine nitrogens. These Fe(III) complexes with deprotonated carboxami do nitrogens are very stable in water.