Ma. Azouni et al., CAPTURE OR REPULSION OF TREATED NYLON PARTICLES BY AN ICE-WATER INTERFACE, Colloids and surfaces. A, Physicochemical and engineering aspects, 122(1-3), 1997, pp. 199-205
In this contribution, we investigate the importance of surface propert
ies in particle entrapment or rejection by an upward moving ice-water
interface. Spherical nylon particles of diameter ranging from 3 x 10(-
3) to 5 x 10(-3) m are used. Some are untreated, some are coated with
a thin layer of carbon or gold and some are soaked in ethanol for seve
ral days before testing. According to the surface state, a particle ma
y be more or less rejected under the same experimental conditions. For
instance, nylon + carbon particles are more easily repulsed than nylo
n particles. For nylon + gold particles, entrapment is favoured. These
experimental results are discussed and compared to our theoretical wo
rk based on the calculation of the different forces acting on untreate
d and treated particles (disjoining force and viscous force).