Auger and X-ray photoelectron spectra of palladium and palladium oxide were
recoded with a MgK alpha primary X-ray source. The Pd3d(5/2) binding energ
ies are 335.4 eV and 336.8 eV for Pd and PdO respectively. While the most w
idely used M-4,M-5 VV Auger structure is rather well defined for pure Pd, w
ith a peak maximum measured at a kinetic energy of 327.5 eV, this is not th
e case for PdO. Consequently, it is difficult to compare the Pd3d-MVV Auger
parameters of these two compounds. This is mainly due to the strong change
s evidenced in the structure of the valence band. On the contrary. the shap
e of the less intense M4,5N2,3N2,3 Auger peak, which implies only the Pd3d
and the Pd4p core levels, does not change much between Pd and PdO. The maxi
mum of the MNN Auger peak is measured at 242.8 eV and 240.5 eV for Pd and P
dO respectively. (C) 1999 Elsevier Science B.V. All rights reserved.