a-Si:C:N:H thin films have been deposited at room temperature by r.f. react
ive-sputtering of a Si target in an Ar+H-2+N-2+CH4 gas mixture. Fourier tra
nsform infrared-absorption spectroscopy and optical absorption spectra have
been investigated for the films. The study shows that the film structure a
nd optical, electrical properties are obviously modified readily by control
ling the process parameters of deposition. The nitrogen-rich a-Si:C:N:H fil
ms are thermally stable within the temperature ranging from 200 to 800 degr
ees C. They are of interest for the potential applications in electronic de
vices.