CHLOROPOLYFLUORO-DERIVATIVES OF ETHYL METHYL-ETHER

Authors
COE PL ROWBOTHAM RA TATLOW JC
Citation
Pl. Coe et al., CHLOROPOLYFLUORO-DERIVATIVES OF ETHYL METHYL-ETHER, Journal of fluorine chemistry, 82(1), 1997, pp. 9-12
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
82
Issue
1
Year of publication
1997
Pages
9 - 12
Database
ISI
SICI code
0022-1139(1997)82:1<9:COEM>2.0.ZU;2-#
Abstract
Fluorination of 2-chloroethyl methyl ether by potassium tetrafluorocob altate at 180-250 degrees C gave various tri-, tetra-, penta- and hexa fluoro(2-chloroethyl methyl) ethers. Cobalt trifluoride afforded the s ame products in poorer recoveries. Structures were established spectre scopically. Cl-2-UV and CHClFCHFOCHF2 gave halogeno-ethers by exchange of Cl for both H and also F. (C) 1997 Elsevier Science S.A. All right s reserved.