S. Rudiger et K. Seppelt, ON REACTIONS OF CARBON-DISULFIDE INDUCED BY NAKED FLUORIDE .1. REACTIONS WITH FLUOROAROMATICS, Journal of fluorine chemistry, 82(1), 1997, pp. 25-28
On reaction with carbon disulphide and tetramethylammonium fluoride in
dimethylformamide, pentafluorobenzonitrile undergoes nucleophilic sub
stitution reactions, resulting eventually in trifluoromethylthio subst
ituted polyfluorobenzonitrile. 2,4-Dinitrofluorobenzene and pentafluor
obenzene undergo similar substitutions, however, the product mixtures
are much more complex. (C) 1997 Elsevier Science S.A. All rights reser
ved.