ELECTROCHEMICAL SYNTHESIS OF DIETHYL FLUOROMETHANEPHOSPHONATE

Authors
TOMILOV AP MARTYNOV BI SMIRNOV YD SEMCHENKO FM
Citation
Ap. Tomilov et al., ELECTROCHEMICAL SYNTHESIS OF DIETHYL FLUOROMETHANEPHOSPHONATE, Journal of fluorine chemistry, 82(1), 1997, pp. 39-41
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
82
Issue
1
Year of publication
1997
Pages
39 - 41
Database
ISI
SICI code
0022-1139(1997)82:1<39:ESODF>2.0.ZU;2-E
Abstract
The electrochemical reduction of diethyl chlorofuloromethanephosphonat e has been studied. It has been shown that, in mildly basic media (pH 7.5-8) of water-alcohol solutions, replacement of the chlorine of the starting compound by hydrogen occurs at lead, cadmium and zinc electro des with high selectivity. The procedure affording diethyl fluorometha nephosphonate in a yield of 85%-90% has been elaborated. (C) 1997 Else vier Science S.A. All rights reserved.