Citation
I. Novak et V. Huang, Photoelectron spectroscopy of lactams, J PHYS ORG, 12(5), 1999, pp. 388-391
Citations number
7
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY
ISSN journal
08943230
→ ACNP
Volume
12
Issue
5
Year of publication
1999
Pages
388 - 391
Database
ISI
SICI code
0894-3230(199905)12:5<388:PSOL>2.0.ZU;2-D
Abstract
He I and He II photoelectron spectra (UPS) of several lactams were measured
and analyzed on the basis of empirical arguments and ab initio calculation
s. The electronic and molecular structure of the amide group is discussed o
n the basis of experimental and theoretical results. Relative basicities of
nitrogen centre(s) are also discussed within the framework of inductive an
d resonance effects. Copyright (C) 1999 John Wiley & Sons, Ltd.