Synthesis and properties of copper(II) phthalocyanines with monoazacrown and crown ethers as peripheral substituents

Authors
Kandaz, M Bekaroglu, O
Citation
M. Kandaz et O. Bekaroglu, Synthesis and properties of copper(II) phthalocyanines with monoazacrown and crown ethers as peripheral substituents, J PORPHYR P, 3(5), 1999, pp. 339-345
Citations number
30
Categorie Soggetti
Chemistry
Journal title
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
ISSN journal
10884246 → ACNP
Volume
3
Issue
5
Year of publication
1999
Pages
339 - 345
Database
ISI
SICI code
1088-4246(199906)3:5<339:SAPOCP>2.0.ZU;2-8
Abstract
Soluble and less soluble phthalocyaninatocopper(II) derivatives (4a and 4b) were prepared from the corresponding 7-[(4'-benzo-15-crown-5)oyl]-15, 16-d ibromo-2,3,6,7,8,9,11,12-octahydro-5H-benzo[e]-12-octahydro-5H-benzo[e]-[1, 4,10,13,7] tetraoxaazacyclopentadecine (3a) and 7-(2'-tosylaminoethyl)-15, 16-dibromo-2,3,6,7,8,9,11,12-octahydro-5H-benzo[e]-[1,4,10,13,7] tetraoxaaz acyclopentadecine (3b) and CuCN in pyridine. A less soluble novel multifunc tionalized scorpiand macrocycle-substituted phthalocyanine (4c) in which an NH2CH2CH2- chain is appended to a monoazacrown ether ring was obtained by detosylation of 4b with concentrated sulfuric acid. Copyright (C) 1999 John Wiley & Sons, Ltd.