Estimation of uncertainties in XAFS data

Citation
M. Newville et al., Estimation of uncertainties in XAFS data, J SYNCHROTR, 6, 1999, pp. 264-265
Citations number
3
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
JOURNAL OF SYNCHROTRON RADIATION
ISSN journal
09090495 → ACNP
Volume
6
Year of publication
1999
Part
3
Pages
264 - 265
Database
ISI
SICI code
0909-0495(19990501)6:<264:EOUIXD>2.0.ZU;2-E
Abstract
The estimate of measurement uncertainties in XAFS spectra is one of the mos t important and difficult aspects of error analysis for XAFS data. Since se veral different analysis methods are used to determine structural parameter s and their uncertainties from XAFS data, and no universally agreed-upon st andard exists, the ability to compare estimates of uncertainties from diffe rent methods is vital. We discuss numerical aspects of the propagation of m easurement uncertainties from raw absorption coefficient to analyzed signal in k- and R-space. We focus our attention on the conversion of measurement uncertainties between k- and R-space representations of XAFS data, and on the testing of this conversion procedure for data dominated by random fluct uations.