EXAFS and principal component analysis: a new shell game

The use of principal component (factor) analysis for the interpretation of EXAFS spectra is described. The components derived from EXAFS spectra share mathematical properties with the original spectra. As a result, the abstra ct components can be analyzed using standard EXAFS methodology to yield bon d distances and other coordination parameters. The number of components tha t must be analyzed is usually less than the number of original spectra. The method is demonstrated using a series of spectra from aqueous solutions of uranyl ions.