Ja. Gupta et al., Layer perfection in ultrathin MOVPE-grown InAs layers buried in GaAs(001) studied by X-ray standing waves and photoluminescence spectroscopy, J SYNCHROTR, 6, 1999, pp. 500-502
Using the In-L fluorescence produced by normal-incidence X-ray standing wav
es, we have measured the layer perfection and positions of 1 and 1/2 monola
yer (ML) InAs quantum wells buried in GaAs(001). Growth temperature effects
were studied in a series of samples produced by metalorganic vapor phase e
pitaxy (MOVPE) at temperatures between 400 and 600 degrees C. The coherent
position of the In atoms decreases with temperature in the 1 ML samples, an
d the optimal growth temperature is near 550 degrees C, as evidenced by the
coherent position of 1.15+/-0.02, and the relatively high coherent fractio
n of 0.72+/-0.08. These results are corroborated by 1.6 K photoluminescence
(PL) measurements in which the most sharp and intense In-excitonic emissio
n is obtained from a sample grown at 530 degrees C. For the 1/2 ML samples,
growth temperatures of 400 degrees C and 600 degrees C produce similar sta
nding wave results: coherent positions of 1.09+/-0.02 and 1.10+/-0.02, cohe
rent fractions of 0.75+/-0.10 and 0.74+/-0.11, respectively. However, PL re
veals the higher temperature sample to be of far superior quality, due to e
xcessive carbon incorporation at 400 degrees C.