The effect of solvent on the structure of the transition metal complexes in solution

Authors
Erenburg, SB Bausk, NV Zemskova, SM Mazalov, LN
Citation
Sb. Erenburg et al., The effect of solvent on the structure of the transition metal complexes in solution, J SYNCHROTR, 6, 1999, pp. 582-584
Citations number
12
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
JOURNAL OF SYNCHROTRON RADIATION
ISSN journal
09090495 → ACNP
Volume
6
Year of publication
1999
Part
3
Pages
582 - 584
Database
ISI
SICI code
0909-0495(19990501)6:<582:TEOSOT>2.0.ZU;2-X
Abstract
CdK EXAFS, ZnK and CuK EXAFS and XANES spectra were measured for solutions of cadmium, zinc and copper dialkyldithiocarbamates in organic solvents wit h varying donating abilities: benzene, pyridine, tributylphosphine and for some model compounds. The parameters of the local surroundings of the Cd, Z n and Cu atoms For complex forms in solutions were determined using EXAFS s pectroscopy. Spatial structure models of the complex forms in a metal chela te - nonaqueous solvent system are suggested.