We have performed Cr and Co K-edge x-ray-absorption measurements to investi
gate the dependence of local electronic and atomic structures on the Cr-lay
er thickness in epitaxial Co (40 Angstrom)/Cr (t(Cr)) (t(Cr) = 2, 3, 5, 7,
and 9 Angstrom) multilayers. The Cr K x-ray absorption near edge structure
(XANES) spectra of Co/Cr multilayers indicate an abrupt transition of the C
r layer from a bcc structure to a hcp structure when the thickness of the C
r layer is decreased down to similar to 5 Angstrom or three atomic layers.
The structural transition and bond-length distortion in Cr and Co layers ob
served in the extended x-ray absorption fine structure (EXAFS) measurements
are consistent with the XANES results.