Nl. Saini et al., Local structure and T-c suppression in Bi2Sr2Ca1-xYx(Cu1-yZny)(2)O8+delta superconductor at 1/8 doping, J SYNCHROTR, 6, 1999, pp. 752-754
Local structural studies on the Bi2Sr2Ca1-xYx(Cu1-yZny)(2)O8+delta supercon
ductor have been carried out by Cu K-edge X-ray absorption spectroscopy. Th
e Cu K-edge XANES spectra show a systematic evolution with the hole doping
for y=0.0 while there is anomalous relaxation of the CuO2 plane in the unde
rdoped regime for y=0.025. Our results suggest that the 1/8 doping is a spe
cial doping below which the local structure of the CuO2 plane shows strong
sensitivity to extrinsic effects. The XANES features, associated with local
structural distortions of the CuO2 plane are discussed.