A metallated primary arsine; synthesis and structure of [PhAsHLi center dot 2thf](infinity)

Authors
Beswick, MA Lawson, YG Raithby, PR Wood, JA Wright, DS
Citation
Ma. Beswick et al., A metallated primary arsine; synthesis and structure of [PhAsHLi center dot 2thf](infinity), J CHEM S DA, (12), 1999, pp. 1921-1922
Citations number
28
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
03009246 → ACNP
Issue
12
Year of publication
1999
Pages
1921 - 1922
Database
ISI
SICI code
0300-9246(19990621):12<1921:AMPASA>2.0.ZU;2-1
Abstract
The lithium primary arsenide [PhAsHli . 2thf](infinity), obtained by reacti on of (BuLi)-Bu-n with PhAsH2 in toluene-thf, crystallises in the form of h elical polymers; the structure of the right-hand enantiomorph has been obta ined.