The surface morphology and absorption edges of epitaxial AlXGa1-XN layers g
rown on (0001) sapphire substrate by molecular beam epitaxy are investigate
d with the change of AlN mole fractions. Transmission and photothermal defl
ection spectroscopy determine the absorption coefficient at room temperatur
e. Photothermal deflection spectroscopy can be applied to determine the low
absorbance values. The uniform depth profile and linear dependence of aver
age atomic concentration of epitaxial AlXCa1-X N layers on AlN mole fractio
n imply that the epitaxial growth of AlXGa1-XN layers with variation of AlN
mole fraction is well controlled without the compositional fluctuation in
depth of the epilayer. It is observed by atomic force microscopy that the s
urface grain shape and roughness of epitaxial AlXGa1-XN layers change at a
middle of AlN mole fraction, and also observed that the effective bandgaps
increase with increasing AlN mole fraction.