This paper deals with the sulfur-accelerated vulcanization of natural rubbe
r using the model compound vulcanization approach. Squalene was the model m
olecule chosen, and a curing system containing a combination of two differe
nt accelerator types. Such a combination is known to give a synergetic effe
ct in both the processing and the final properties of the vulcanizate, The
vulcanization process was characterized using HPLC, GPC, and MS.