S. Pikin et al., The semi-phenomenological model of antiferroelectricity in chiral smectic liquid crystals - II. The phase transitions and phase diagrams, LIQ CRYST, 26(8), 1999, pp. 1115-1122
In the framework of the model of short pitch modes (SPM) developed for chir
al smectics with inclined molecules, the phase transitions and diagrams in
antiferroelectric systems are described. It is shown that the families of a
ntiferro- and ferri-electric phases are controlled by a few physical parame
ters such as the smectic correlation length and the chirality parameter. Th
e sequences of antiferro- and ferri-electric states are explained as being
dependent on the interactions between SPM and the conventional long pitch m
ode (LPM), the ferrielectric states being described in terms of the obvious
coexistence of LPM and several SPM.