Atoms in light crystals formed by a standing light wave are a model system
to study the propagation of matter waves in periodic potentials. The encoun
tered phenomena can be described by dynamical diffraction theory which has
been extensively studied for x-ray, electron, and neutron scattering from s
olid state crystals. In this paper we show that an atomic de Broglie wave t
raversing a standing light wave allows investigation of predictions of dyna
mical diffraction theory which were previously experimentally not accessibl
e. We present standard diffraction efficiency characterizations for pure ab
sorptive and pure refractive crystals. Additionally we were able to measure
directly the total atomic wave field formed inside a refractive and on abs
orptive crystal and to confirm the predicted absolute position of the atomi
c wave field with respect to the lattice planes. By superposing two standin
g light waves of different frequency we tailored a new kind of crystal pote
ntial where Friedel's law about usual diffraction symmetries is maximally v
iolated. [S1050-2947(99)02207-6].