A stereoselective synthetic route to (E)-2-arylvinylphosphonates

Authors
Zhong, P Huang, X Xiong, ZX
Citation
P. Zhong et al., A stereoselective synthetic route to (E)-2-arylvinylphosphonates, SYNLETT, (6), 1999, pp. 721-722
Citations number
15
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNLETT
ISSN journal
09365214 → ACNP
Issue
6
Year of publication
1999
Pages
721 - 722
Database
ISI
SICI code
0936-5214(199906):6<721:ASSRT(>2.0.ZU;2-W
Abstract
Terminal alkynes 1 react with Cp2Zr(H)Cl ( Cp = eta(5) - C5H5) to give orga nozirconium (IV) complexes 2, which are trapped with dialkyl chlorophosphat es to afford (E)-arylvinylphosphonates 3.