Synthesis of tetrasubstituted ethylenic compounds from a gem-trichloroimidazole derivative by electron transfer reactions

Authors
Vanelle, P Benakli, K Giraud, L Crozet, MP
Citation
P. Vanelle et al., Synthesis of tetrasubstituted ethylenic compounds from a gem-trichloroimidazole derivative by electron transfer reactions, SYNLETT, (6), 1999, pp. 801-803
Citations number
21
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNLETT
ISSN journal
09365214 → ACNP
Issue
6
Year of publication
1999
Pages
801 - 803
Database
ISI
SICI code
0936-5214(199906):6<801:SOTECF>2.0.ZU;2-1
Abstract
New 5-nitroimidazoles bearing a tetrasubstituted ethylenic double bond in 2 -position were synthesized in high yields by the reaction of secondary nitr onate anions with a new reductive alkylating agent, 1-methyl-2-trichloromet hyl-5-nitroimidazole Consecutive S(RN)1 and E(RC)1 mechanisms were followed in these processes.