Asymmetric synthesis of amino sugars. Part 1: Stereoselective synthesis of(2S,3S,4R,5S)-2-amino-1,3,4,5,6-hexanepentol derivatives and their conversion to L-mannosamine derivatives
L. Ermolenko et al., Asymmetric synthesis of amino sugars. Part 1: Stereoselective synthesis of(2S,3S,4R,5S)-2-amino-1,3,4,5,6-hexanepentol derivatives and their conversion to L-mannosamine derivatives, TETRAHEDR L, 40(28), 1999, pp. 5187-5190
A novel approach for asymmetric synthesis of amino sugars is developed, sta
rting from readily available chiral building blocks 1 and 2,3-O-isopropylid
eneglyceraldehyde 2, via the Julia olefination and subsequent dihydroxylati
on as key steps. (C) 1999 Published by Elsevier Science Ltd. All rights res
erved.