Lf. Sun et al., Structure and morphology of carbon nanotubes grown on zeolite-supported catalysts by chemical vapor deposition, ACT PHY C E, 8(7), 1999, pp. 545-550
The zeolite-supported catalysts were prepared in nickel and cobalt nitrate
aqueous solutions by ion exchange method. After reducing these substrates b
y hydrogen, we grew carbon nanotubes on them by chemical vapor deposition u
nder different conditions. The results reveal that nickel/zeolite, cobalt/z
eolite and nickel+cobalt/zeolite have different optimal conditions. When ni
ckel+cobalt/zeolite was used as the catalyst, we can get straight carbon na
notubes. The Raman spectrum of the straight nanotubes shows they have fewer
defects. We propose a growth mechanism for the growth of these nanotubes.