Oxidation behavior of Ni in molten carbonate

Authors
Motohira, N Takai, T Kamiya, N Ota, K
Citation
N. Motohira et al., Oxidation behavior of Ni in molten carbonate, B CHEM S J, 72(6), 1999, pp. 1403-1407
Citations number
9
Categorie Soggetti
Chemistry
Journal title
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
ISSN journal
00092673 → ACNP
Volume
72
Issue
6
Year of publication
1999
Pages
1403 - 1407
Database
ISI
SICI code
0009-2673(199906)72:6<1403:OBONIM>2.0.ZU;2-M
Abstract
The oxidation behavior of Ni in molten carbonate was evaluated by chronopot entiometry. The oxidation of Ni in molten carbonate proceeded in a two-step reaction. The first step of oxidation was independent of the specimens' na ture and depended on P-CO2. On the other hand, the second step of oxidation depended on the batch of the specimens, and was independent of P-CO2. The corrosion product in both oxidation processes was divalent Ni oxide, namely NiO.