The various states formed by positive muons implanted into phosphorus
and sulphur have been characterized as a model for interstitial hydrog
en, of which little is known in these elements. Repolarization studies
reveal muonium-like states in each case, giving estimates of the hype
rfine parameters and, for sulphur at least, an indication of the coexi
stence of a molecular radical state. The longitudinal-field relaxation
functions suggest conversion of the paramagnetic states to diamagneti
c, i.e. ionization or chemical reaction, in competition with strong sp
in-lattice relaxation.