The effect of deuteration on ferroelastic-ferroelastic phase transitions an
d ferroelastic domain structure in (NH4)(3)H(SeO4)(2) was investigated. Cry
stals of various degrees of deuteration were studied. The temperature width
of ferroelastic triclinic phase was found to decrease with increasing degr
ee of deuteration. The temperature of superionic (2) - ferroelastic (1) pha
se transition lowered from 306 K for the non-deuterated crystal to 293 K fo
r the crystal with the highest degree of deuteration. Additional result of
deuteration was a change in the pattern of domain structure in the ferroela
stic (1) - ferroelastic (2) phase.