In a high volume fraction particle-loaded piezocomposite, some ferroelectri
c particles appear to be in contact, as in a 3-3 connectivity material; oth
ers are isolated in the polymer matrix, as in a pure 0-3 connectivity mater
ial. Such a material can be considered as a composite of composites charact
erized by a 3-3(0-3) connectivity. This paper follows two others that have
described a matrix method to calculate all of the effective parameters of p
ure 0-3 and 3-3 connectivity piezocomposites. These previous models are use
d to obtain the effective properties of a 3-3(0-3) composite. A proportion
of 0-3 connectivity in the composite is introduced, and the effective prope
rties are studied as a function of this proportion. Experimental results co
mpared with these predictions show that the model allows an evaluation of t
he proportion of 0-3 connectivity through the analysis of the electromechan
ical performance of the composite samples.