Metallaborane reaction chemistry Part 8. Phenylacetylene trimerisation by [6,6,6-(PPh3)(2)H-nido-6-IrB9H13] and the structure of [2-(eta(6)-C6H3Ph3)-closo-2-IrB9H8-10-(PPh3)] by synchrotron X-ray diffraction analysis

Authors
Bould, J Clegg, W Spalding, TR Kennedy, JD
Citation
J. Bould et al., Metallaborane reaction chemistry Part 8. Phenylacetylene trimerisation by [6,6,6-(PPh3)(2)H-nido-6-IrB9H13] and the structure of [2-(eta(6)-C6H3Ph3)-closo-2-IrB9H8-10-(PPh3)] by synchrotron X-ray diffraction analysis, INORG CH C, 2(7), 1999, pp. 315-318
Citations number
30
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
2
Issue
7
Year of publication
1999
Pages
315 - 318
Database
ISI
SICI code
1387-7003(199907)2:7<315:MRCP8P>2.0.ZU;2-#
Abstract
The microwave-heated reaction between PhC drop CH and [6,6,6-(PPh3)(2)H-nid o-6-IrB9H13] gives [2-(eta(6)-C6H3Ph3)-closo-2-IrB9H6-10(PPh3)] (29%) and t hereby demonstrates acetylene trimerisation on a metallaborane matrix. (C) 1999 Elsevier Science S.A. All rights reserved.