Investigation of the sodium vanadium bronze NaV6O15 in the presence of carbonyl nickel

Authors
Smirnova, OA Mikhailova, AM Chernova, MA Kosobudskii, ID
Citation
Oa. Smirnova et al., Investigation of the sodium vanadium bronze NaV6O15 in the presence of carbonyl nickel, INORG MATER, 35(7), 1999, pp. 747-749
Citations number
16
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
INORGANIC MATERIALS
ISSN journal
00201685 → ACNP
Volume
35
Issue
7
Year of publication
1999
Pages
747 - 749
Database
ISI
SICI code
0020-1685(199907)35:7<747:IOTSVB>2.0.ZU;2-X
Abstract
Heat treatment of the sodium vanadium bronze NaV6O15 containing conducting and plasticizing additives was found to yield compounds of vanadium in lowe r oxidation states. The resulting phases were identified by x-ray diffracti on analysis. A procedure is proposed for determining V3+, V4+, and V5+ coex isting in mixed-phase materials. X-ray diffraction data correlate with anal ytical results.