P. Nowak, Kinetic aspects of the synthesis of n-penthyl and n-heptyl acrylates in a liquid phase without a catalyst, INZ CHEM PR, 20(2), 1999, pp. 177-184
The results of the esterification of acrylic acid with n-pentanol and n-hep
tanol in the liquid phase without catalyst are presented. The kinetics of t
he esterification has been investigated in an isothermal semibatch reactor.
The kinetic parameters have been determined. The reaction is of second ord
er but the rate of formation of the product depends only on the concentrati
on of acrylic acid.