Experimental investigations of double ionization provide information on the
mechanism by which two electrons can be simultaneously removed from an ato
m. Information on the two-electron momentum distribution function of the el
ectrons can also be obtained from the experiments. Results for the double i
onization of magnesium are summarized and new (e,3e) data presented. Under
a variety of experimental conditions evidence has been found for orientatio
n and polarization effects. In addition, the recoil momentum of the residua
l doubly-charged ion is often large implying large momentum transfer to the
core or ionizing collisions that occur close to the nucleus.