The thermoluminescence of pure and doped LiF crystals has been measured fol
lowing irradiation at ambient temperature with gamma and x rays. Factors in
vestigated include the effects of dopants (Mg, Mg/ Ti, and Fe) and of dose.
Results are compared with optical absorption and photoluminescence measure
ments made previously on the same crystals. The role of F, F-3(+), Z(2), an
d colloids in the emission process is discussed. Some new effects are repor
ted including step-like features in the glow curves at large doses. These a
re explained in terms of the clustering of interstitial defects formed duri
ng radiolysis. (C) 1999 American Institute of Physics. [S0021-8979(99)01315
-8].