EFFECT OF CATIONS IN THE HYDROLYSIS OF PHOSPHATE-ESTERS

Authors
MENTZ M MODRO TA
Citation
M. Mentz et Ta. Modro, EFFECT OF CATIONS IN THE HYDROLYSIS OF PHOSPHATE-ESTERS, Perkin transactions. 2, (12), 1995, pp. 2227-2229
Citations number
12
Categorie Soggetti
Chemistry Physical","Chemistry Inorganic & Nuclear
Journal title
Perkin transactions. 2 → ACNP
ISSN journal
03009580
Issue
12
Year of publication
1995
Pages
2227 - 2229
Database
ISI
SICI code
0300-9580(1995):12<2227:EOCITH>2.0.ZU;2-J
Abstract
The rates of the acid-catalysed hydrolysis of diethyl 2-pyridyl phosph ate and of the base-promoted hydrolysis of N-methyl-8-(dimethylphospho ryloxy)quinolinium ion have been determined in the presence of differe nt cations as buffer components. For both substrates the rate depends on the nature of the cations, indicating the participation of a substr ate-cation complex in the reaction.