Vapor-liquid equilibria for the ternary system acetone plus methanol plus water at 101.325 kPa

Authors
Iglesias, M Orge, B Marino, G Tojo, J
Citation
M. Iglesias et al., Vapor-liquid equilibria for the ternary system acetone plus methanol plus water at 101.325 kPa, J CHEM EN D, 44(4), 1999, pp. 661-665
Citations number
27
Categorie Soggetti
Chemistry,"Chemical Engineering
Journal title
JOURNAL OF CHEMICAL AND ENGINEERING DATA
ISSN journal
00219568 → ACNP
Volume
44
Issue
4
Year of publication
1999
Pages
661 - 665
Database
ISI
SICI code
0021-9568(199907/08)44:4<661:VEFTTS>2.0.ZU;2-2
Abstract
The vapor-liquid equilibrium at 101.325 kPa has been measured for the terna ry system acetone + methanol + water in an equilibrium still with circulati on of phases. Satisfactory results were obtained for the prediction of acti vity coefficients and the equilibrium compositions with group contribution models (ASOG, UNIFAC, UNIFAC-Dortmund, and UNIFAC-Lyngby). Small standard d eviations of vapor molar fraction and temperature were calculated. Azeotrop ic behavior was observed only in the acetone + methanol mixture. The correl ation parameters for the Tamir-Wisniak and UNIQUAC equations were presented .