Vinylphosphonium salt mediated efficient synthesis of dialkyl 1H-pyrrolizine-2,3-dicarboxylates

Citation
I. Yavari et al., Vinylphosphonium salt mediated efficient synthesis of dialkyl 1H-pyrrolizine-2,3-dicarboxylates, J CHEM R-S, (6), 1999, pp. 382-383
Citations number
13
Categorie Soggetti
Chemistry
Journal title
JOURNAL OF CHEMICAL RESEARCH-S
ISSN journal
03082342 → ACNP
Issue
6
Year of publication
1999
Pages
382 - 383
Database
ISI
SICI code
0308-2342(199906):6<382:VSMESO>2.0.ZU;2-K
Abstract
Protonation of the 1:1 intermediate produced in the reaction between triphe nylphosphine and dialkyl acetylenedicarboxylates by pyrrole-2-carbaldehyde leads to a vinylphosphonium salt, which undergoes intramolecular Wittig rea ction to produce the title compounds in good yields.