A novel synthesis of trifluoromethyl ethers via xanthates, utilizing BrF3

Authors
Ben-David, I Rechavi, D Mishani, E Rozen, S
Citation
I. Ben-david et al., A novel synthesis of trifluoromethyl ethers via xanthates, utilizing BrF3, J FLUORINE, 97(1-2), 1999, pp. 75-78
Citations number
19
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF FLUORINE CHEMISTRY
ISSN journal
00221139 → ACNP
Volume
97
Issue
1-2
Year of publication
1999
Pages
75 - 78
Database
ISI
SICI code
0022-1139(19990720)97:1-2<75:ANSOTE>2.0.ZU;2-G
Abstract
Alcohols were transformed into trifluoromethyl ethers by converting them to xanthates in almost quantitative yields followed by a reaction with bromin e trifluoride, a reagent rarely used in organic chemistry. (C) 1999 Elsevie r Science S.A. All rights reserved.