Radical addition reaction of 2-benzoyloxypentafluoropropene onto cycloalkanes

Authors
Narita, T Hagiwara, T Hamana, H Kitamura, K Inagaki, Y Yoshida, Y
Citation
T. Narita et al., Radical addition reaction of 2-benzoyloxypentafluoropropene onto cycloalkanes, J FLUORINE, 97(1-2), 1999, pp. 263-265
Citations number
7
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF FLUORINE CHEMISTRY
ISSN journal
00221139 → ACNP
Volume
97
Issue
1-2
Year of publication
1999
Pages
263 - 265
Database
ISI
SICI code
0022-1139(19990720)97:1-2<263:RARO2O>2.0.ZU;2-V
Abstract
The radical addition reactions of 2-benzoyloxypentafluoropropene [CF2=C(CF3 )OCOC6H5] (BPFP), an F-enol ester, with cyclopentane, cyclohexane and cyclo heptane in the presence of benzoyl peroxide are shown to afford the 1:1 add ition products of BPFP with the cycloalkanes. The structures of the reactio n products were confirmed by the mass spectra and H-1, C-13 and F-19 NMR me asurements. Similar additions of perfluoroisopropenyl cyclohexanecarboxylat e with cycloalkanes were also investigated. (C) 1999 Elsevier Science S.A. All rights reserved.